RESUMO
While colloidal chemistry provides ways to obtain a great variety of nanoparticles with different shapes, sizes, material compositions, and surface functions, their controlled deposition and combination on arbitrary positions of substrates remain a considerable challenge. Over the last ten years, optical printing arose as a versatile method to achieve this purpose for different kinds of nanoparticles. In this article, we review the state of the art of optical printing of single nanoparticles and discuss its strengths, limitations, and future perspectives by focusing on four main challenges: printing accuracy, resolution, selectivity, and nanoparticle photostability.
RESUMO
In a tightly focused beam of light having both spin and orbital angular momentum, the beam exhibits the spin-orbit interaction phenomenon. We demonstrate here that this interaction gives rise to series of subtle, but observable, effects on the dynamics of a dielectric microsphere trapped in such a beam. In our setup, we control the strength of spin-orbit interaction with the width, polarization and vorticity of the beam and record how these parameters influence radius and orbiting frequency of the same single orbiting particle pushed by the laser beam. Using Richard and Wolf model of the non-paraxial beam focusing, we found a very good agreement between the experimental results and the theoretical model based on calculation of the optical forces using the generalized Lorenz-Mie theory extended to a non-paraxial vortex beam. Especially the radius of the particle orbit seems to be a promising parameter characterizing the spin to orbital momentum conversion independently on the trapping beam power.
RESUMO
Optical printing is a powerful all-optical method that allows the incorporation of colloidal nanoparticles (NPs) onto substrates with nanometric precision. Here, we present a systematic study of the accuracy of optical printing of Au and Ag NPs, using different laser powers and wavelengths. When using light of wavelength tuned to the localized surface plasmon resonance (LSPR) of the NPs, the accuracy improves as the laser power is reduced, whereas for wavelengths off the LSPR, the accuracy is independent of the laser power. Complementary studies of the printing times of the NPs reveal the roles of Brownian and deterministic motion. Calculated trajectories of the NPs, taking into account the interplay between optical forces, electrostatic forces, and Brownian motion, allowed us to rationalize the experimental results and gain a detailed insight into the mechanism of the printing process. A clear framework is laid out for future optimizations of optical printing and optical manipulation of NPs near substrates.