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Introducción: El noroeste de Costa Rica representa un área con una alta riqueza geológica que evidencia rocas generadas en diferentes ambientes, como plano abisal, talud continental, plataforma continental, volcánicos continentales efusivos y explosivos, volcánicos submarinos, costeros, erosivos fluviales, erosivos gravitatorios, de intrusión y el manto terrestre. Objetivo: Describir el contexto geológico actual del noroeste de Costa Rica, mediante el análisis y recopilación de datos de campo, geoquímicos, petrológicos, estructurales, paleontológicos y radiométricos con el fin de reconstruir los eventos y etapas de deformación desde el Jurásico a la actualidad. Métodos: Se hizo una recopilación bibliográfica de estudios en diversas ramas geológicas para establecer un estado del arte del extremo noroeste de Costa Rica. Resultados: La historia geológica representa el registro en rocas desde el Jurásico al Holoceno - actualidad con once etapas definidas a partir de interpretaciones petrológicas, estructurales, geocronológicas, estratigráficas y paleontológicas agrupadas en tres etapas de depositación y afectadas por cuatro fases tectónicas compresivas. Conclusiones: Las etapas de depositación corresponden con una primera etapa magmática con afinidad oceánica entre el Jurásico y el Cretácico Superior, una segunda etapa predominantemente sedimentaria con un rango de edad entre el Cretácico Superior y el Oligoceno, y por último una etapa volcánica efusiva - explosiva ubicada desde el Plioceno hasta la actualidad. Las fases tectónicas se asocian con diferentes eventos entre placas. La primera se dio en el Cretácico Inferior y su principal resultado visible fue la emersión de la Ofiolita de Santa Elena; la segunda sucedió del Cretácico Superior temprano al Campaniano y su reconocimiento está ligado a la posición actual de la Ofiolita de Santa Elena y sus estructuras circundantes; la tercera fase aconteció desde el Eoceno Superior hasta el Mioceno y su principal producto fue la generación del tren de pliegues sedimentarios del Golfo de Santa Elena a bahía de Salinas; y por último se presenta una fase Cuaternaria que originó el eje de basculamiento de los productos piroclásticos frente a la cordillera volcánica de Guanacaste.

Introduction: The Costa Rican northwestern coastline has a wide geological uniqueness that exhibits rocks from different environments such as abyssal plane, continental slope, continental platform, volcanic eruptions (effusive, explosive, and submarine), coastal, erosional (fluvial and gravitatory), intrusions, and upper mantle rocks. Objective: To present the geologic state of the art of the northwestern coastline of Costa Rica through the bibliographic review of geochemical, petrologic, structural, paleontological and geochronological data. Methods: A bibliographic revision was done to propose a state of the art of northwestern coastline of Costa Rica. Results: The geologic record shows eleven stages from the Jurassic to the Holocene. These stages were regrouped from petrologic, structural, geochronologic, stratigraphic and paleontological interpretations in three depositional stages and four compressive tectonic phases. Conclusions: The first depositional stage is volcanic with oceanic affinity between the Jurassic and Upper Cretaceous. The second has a sedimentary predominance with an age range between the Upper Cretaceous and the Miocene. The last depositional stage is a volcanic (effusive and explosive) from the Pliocene until the present. The tectonic phases are associate with different interactions between tectonic plates. The first phase triggered the Santa Elena Ophiolite obduction during the Early Cretaceous. The second phase occurred in the Early Upper Cretaceous - Campanian and is recognized by its current position and surrounding structures. The third phase lasted from the Upper Eocene until the Miocene and its main result was the folding of the Bahía de Salinas sedimentary rocks. Finally, the Quaternary phase created a tilt axis and the aperture for the deposition of pyroclastic density currents in front of the Guanacaste volcanic ridge.

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The contribution of Hg from volcanic emanations is decisive for assessing global mercury emissions given the impact of this highly toxic contaminant on human health and ecosystems. Atmospheric Hg emissions from Popocatépetl volcano and their dispersion were evaluated carrying out two gaseous elemental mercury (GEM) surveys during a period of intense volcanic activity. Continuous GEM measurements were taken for 24 h using a portable mercury vapor analyzer (Lumex RA-915M) at the Altzomoni Atmospheric Observatory (AAO), 11 km from the crater. In addition, a long-distance survey to measure GEM was conducted during an automobile transect around the volcano, covering a distance of 129 km. The evaluation of the GEM data registered in the fixed location showed that heightened volcanic activity clearly intensifies the concentration of atmospheric Hg, extreme values around 5 ng m-3. Highest concentrations of GEM recorded during the mobile survey were about 10 ng m-3. In both surveys, the recorded concentrations during most of the measurement time were below 2 ng m-3, but measurements were taken at a considerable distance from the crater, and GEM is subject to dilution processes. During both surveys, recorded GEM did not exceed the 200 ng m-3 concentration recommended by the WHO (Air quality guidelines for Europe, 2000) as the regulatory limits for Hg in the atmospheric environment for long-term inhalation. Because this study was carried out in inhabited areas around the volcano during a period of intense volcanic activity, it can be concluded that the Popocatépetl does not represent a risk to human health in terms of Hg.

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The Paraná-Etendeka Magmatic Province is associated with the distensive tectonics that caused the rupture of the Gondwana continent during the Lower Cretaceous and generated an intense volcanism that covers South America and the NW portion of Namibia in Africa. In Brazil, this volcanic sequence is named Serra Geral Group and predominantly consists of basalts and subordinated silicic rocks. The goal of this study is to characterize the geomorphological features observed in the Aparados da Serra region, southern Brazil, and to evaluate the relationship between these structures and the primary silicic volcanic structures. The geomorphological features were first identified using remote sensing and then correlated with flow structures observed in the field, as well as petrographic and geochemical data. AMS data were used to determine magnetic patterns and the direction of magmatic flow of the rocks. Despite the low degree of anisotropy, clear patterns of lineation and foliation were identified in the studied rocks. Our data shows that Units I and II correspond to silicic lava flows linked to effusive fissure eruptions, presenting a dome morphology caused by differential erosion. Unit III rocks may correspond to true volcanic domes, whereas the Unit IV corresponds to the effusive feeder structures.

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This study investigates the immediate and mid-term effects of the biogeochemical variables input into the Reloncaví fjord (41°40'S; 72°23'O) as a result of the eruption of Calbuco volcano. Reloncaví is an estuarine system supporting one of the largest mussels farming production within Northern Chilean-Patagonia. Field-surveys were conducted immediately after the volcanic eruption (23-30 April 2015), one month (May 2015), and five months posterior to the event (September 2015). Water samples were collected from three stations along the fjord to determine greenhouse gases [GHG: methane (CH4), nitrous oxide (N2O)], nutrients [NO3-, NO2-, PO43-, Si(OH)4, sulphate (SO42-)], and carbonate systems parameters [total pH (pHT), temperature, salinity, dissolved oxygen (O2), and total alkalinity (AT)]. Additionally, the impact of physicochemical changes in the water column on juveniles of the produced Chilean blue mussel, Mytilus chilensis, was also studied. Following the eruption, a large phytoplankton bloom led to an increase in pHT, due to the uptake of dissolved-inorganic carbon in photic waters, potentially associated with the runoff of continental soil covered in volcanic ash. Indeed, high surface SO42- and GHG were observed to be associated with river discharges. No direct evidence of the eruption was observed within the carbonate system. Notwithstanding, a vertical pattern was observed, with an undersaturation of aragonite (ΩAr < 1) both in brackish surface (<3 m) and deep waters (>10 m), and saturated values in subsurface waters (3 to 7 m). Simultaneously, juvenile mussel shells showed maximized length and weight at 4 m depth. Results suggest a localized impact of the volcanic eruption on surface GHG, nutrients and short-term effects on the carbonate system. Optimal conditions for mussel calcification were identified within a subsurface refuge in the fjord. These specific attributes can be integrated into adaptation strategies by the mussel aquaculture industry to confront ocean acidification and changing runoff conditions.

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The present study addresses the metal concentration pattern and associated human health risks in ash samples of Popocatepetl volcano. In this regard, 12 ash samples from different regions of Puebla City were collected and analyzed for 28 major and trace metals, out of which exclusively 8 metals of potential risk (Cd, Co, Cr, Cu, Mn, Ni, Pb & Zn) were selected for human health risk validation. The metal concentration pattern showed an enriching trend for ferromagnesium and carbonate elements compared to previous ash eruptions. Enrichment factor and geoaccumulation indices displayed a least significant enhancement of metals from baseline concentrations. More likely, the potential ecological risk index suggested no harmful biological effects due to the presence of these metals in ash. Concurrently, in the human health risk assessment model, the hazard quotient and hazard index values < 1 indicated safe levels and no carcinogenic effects. All-inclusive, this study highlights the context of metals in ash fall of Popocatepetl which presents no adverse effects over the human population.

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Lake Nahuel Huapi (NH) is a large, ultraoligotrophic deep system located in Nahuel Huapi National Park (NHNP) and collecting a major headwater network of Northwestern Patagonia (Argentina). Brazo Rincón (BR), the westernmost branch of NH, is close to the active volcanic formation Puyehue-Cordón Caulle. In BR, aquatic biota and sediments display high levels of total Hg (THg), ranging in contamination levels although it is an unpolluted region. In this survey, Hg species and fractionation were assessed in association with dissolved organic matter (DOM) in several aquatic systems draining to BR. THg varied between 16.8 and 363 ng L-1, with inorganic Hg (Hg2+) contributing up to 99.8% and methyl mercury (MeHg) up to 2.10%. DOC levels were low (0.31-1.02 mg L-1) resulting in high THg:DOC and reflecting in high Hg2+ availability for binding particles (partitioning coefficient log Kd up to 6.03). In streams, Hg fractionation and speciation related directly with DOM terrestrial prints, indicating coupled Hg-DOM inputs from the catchment. In the lake, DOM quality and photochemical and biological processing drive Hg fractionation, speciation and vertical levels. Dissolved gaseous Hg (Hg0) reached higher values in BR (up to 3.8%), particularly in upper lake layers where solar radiation enhances the photoreduction of Hg2+ and Hg-DOM complexes. The environmental conditions in BR catchment promote Hg2+ binding to abiotic particles and bioaccumulation and the production of Hg0, features enhancing Hg mobilization among ecosystem compartments. Overall, the aquatic network studied can be considered a "natural Hg hotspot" within NHNP.

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Fernando de Noronha is a small volcanic archipelago in the Southern Atlantic, some 350 km NE of the city of Natal in NE Brazil. These remote volcanic islands represent a largely pristine environment, distant from sources of anthropogenic contamination. This study was carried out to determine the natural concentrations of Ag, Ba, Cd, Co, Cr, Cu, Mo, Ni, Pb, Sb, V and Zn in the A and B horizons of soils of Fernando de Noronha. The aims of the study were twofold: determine whether there is a relationship between the bedrock geology and soils and to establish quality reference values for soils from Fernando de Noronha. Soil samples were subjected to acid digestion by the USEPA method 3051A, and metals were determined by inductively coupled plasma emission spectrophotometry. The results showed that the trace element distribution largely reflects the geochemistry of the underlying volcanic rocks of the Remedios and Quixaba Formations. The results demonstrate that the concentrations of Ba, Cr, Zn, Ni and Cu from the soils of the volcanic Fernando de Noronha archipelago are higher than those found in soils from continental Brazil. However, concentrations of Ni, Cu and Co are lower in soils of the archipelago as compared to other volcanic islands throughout the world. The elevated trace element concentrations of the volcanic parent material of Fernando de Noronha soils seem to be the main factor governing the relatively high natural concentrations of trace elements.

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This work supplies a characterization of the chemical properties, including data of dissolved major and minor components in surface and pore water collected in Argentinean lakes surrounding the impacted area of Puyehue-Cordón Caulle volcanic complex, in the 2011 eruption. The principal component analysis and Pollution Load Index were used for the identification of water changes by volcanic ashes deposited throughout 1 year of eruption. The element content between water column and pore water provided a direct evidence of the potential dissolution of the element. Many chemical transformations, after the pyroclastic material contacted with the freshwater, were observed such as large pH changes from 3.2 to 8.1, electrical conductivity of 28.9 to 457 µs/cm, and redox potential of 171 to 591 mV. The maximum concentrations measured of F, Al, and Hg were 600, 40, and 0.0382 µg/L respectively. These concentrations in water column were lower than the limit of aquatic life protection for chronic toxicity. The Pollution Load Index indicated very low pollution for sites far away from the volcano and moderated pollution in closely sites. The processes were stabilized at the end of the monitoring, 1 year after the eruption.

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Cryptotephra (particles <125µm) is a key record for monitoring past and current volcanic activity. However, its extraction from the host sediment and analysis is often long and difficult because of its small size. Finding a simple method to extract cryptotephra from environmental samples would therefore make its analysis much easier. We hypothesized that arcellinid testate amoebae may hold such a potential. These free-living shelled protists are among the earliest microorganisms to colonize volcanic tephra, and build their shell by agglutinating minerals from their environment. We analyzed by X-ray Spectrometry the mineral signature of tephra from the 2011 Puyehue-Cordon Caulle Volcanic Complex (Chile) eruption ash fallout and compared it to that of the shells of 51 individual testate amoebae (three individuals from each of 17 species) from 13 samples collected at different distances from the active vent. The mineral composition of particles within shells closely matched that of similar size class particles from their environment. The capacity of testate amoebae to randomly use mineral grains from their environment makes it possible to use their shells to assess the mineral composition of cryptotephra from soil, peat or sediment samples. Testate amoebae therefore represent the microbial world's version of Cinderella's helping pigeons.

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Volcanic eruptions discharge massive amounts of ash and pumice that decrease light penetration in lakes and lead to concomitant increases in phosphorus (P) concentrations and shifts in soluble C/P ratios. The consequences of these sudden changes for bacteria community composition, metabolism, and enzymatic activity remain unclear, especially for the dynamic period immediately after pumice deposition. Thus, the main aim of our study was to determine how ambient bacterial communities respond to pumice inputs in lakes that differ in dissolved organic carbon (DOC) and P concentrations and to what extent these responses are moderated by substrate C/P stoichiometry. We performed an outdoor experiment with natural lake water from two lakes that differed in dissolved organic carbon (DOC) concentration. We measured nutrient concentrations, alkaline phosphatase activity (APA), and DOC consumption rates and assessed different components of bacterial community structure using next-generation sequencing of the 16S rRNA gene. Pumice inputs caused a decrease in the C/P ratio of dissolved resources, a decrease in APA, and an increase in DOC consumption, indicating reduced P limitation. These changes in bacteria metabolism were coupled with modifications in the assemblage composition and an increase in diversity, with increases in bacterial taxa associated with biofilm and sediments, in predatory bacteria, and in bacteria with gliding motility. Our results confirm that volcanic eruptions have the potential to alter nutrient partitioning and light penetration in receiving waterways which can have dramatic impacts on microbial community dynamics.

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