RESUMO
The increase in the frequency and severity of global wildfires has been largely influenced by climate change and land use changes. From February 2 to 6, 2024, central Chile experienced its most devastating wildland-urban interface wildfire in history, severely impacting the Valparaíso region. This catastrophic event, which led to extensive forest destruction, the loss of thousands of homes, and over a hundred human fatalities, directly impacted the area surrounding the campus of Federico Santa María Technical University. In that period, an air quality monitoring campaign was set up on the campus to measure black carbon (BC) and particulate matter (PM) during the wildfire season. The monitoring station was located directly within the smoke plume, allowing for the collection of unprecedented air quality data. Extremely high concentrations of BC at 880 nm were reported during the wildfires, with a daily mean (±σ) of 14.83 ± 19.52 µg m-3. Peak concentrations measured at 880 nm and 375 nm reached 812.89 µg m-3 and 1561.24 µg m-3, respectively. The maximum daily mean BC concentrations at these wavelengths were 55 and 99 times higher, respectively, compared to the pre-event period. The mean Ångström absorbing coefficient during the event was 1.66, indicating biomass burning as the primary BC source, while the maximum BC/PM2.5 ratio (at 375 nm) reached 57 %. From February 2 to 5, 2024, PM concentrations exceeded the Chilean air quality standard by 82 % and 198 % for coarse and fine particles, respectively. These levels are 4.7 and 6.0 times higher than the World Health Organization's recommendations. These elevated concentrations persisted for up to three days after the fire was extinguished. This study provides unique evidence of the rapid deterioration of regional air quality during a wildfire event using in situ measurements, serving as a stark reminder of the far-reaching consequences of a warming climate.
Assuntos
Poluentes Atmosféricos , Poluição do Ar , Monitoramento Ambiental , Material Particulado , Fuligem , Incêndios Florestais , Material Particulado/análise , Chile , Poluentes Atmosféricos/análise , Fuligem/análise , Poluição do Ar/estatística & dados numéricos , Mudança ClimáticaRESUMO
Glacial bodies in the Peruvian Andes Mountains store and supply freshwater to hundreds of thousands of people in central Peru. Atmospheric black carbon (BC) is known to accelerate melting of snow and ice, in addition to contributing to air pollution and the health of people. Currently there is limited understanding on the sources and temporal variability of BC in valley and mountain environments in Peru. To address this problem, this study combined surface observations of BC collected during 2022-2023 with WRF model simulations and HYSPLIT trajectories to analyze the dispersion and sources of BC in valley and high elevation environments and the associated local atmospheric circulations. Results show high BC concentrations are associated with the valley-mountain wind system that occurs on both sides of the Huaytapallana mountain range. A pronounced circulation occurs on the western slopes of Huaytapallana when concentrations of BC increase during daylight hours, which transports atmospheric pollutants from cities in the Mantaro River Valley to the Huaytapallana mountain range. Low concentrations of BC are associated with circulations from the east that are channeled by the pronounced ravines of the Andes-Amazon transition. On average, during the season of highest BC concentrations (July-November), the relative contributions of fossil fuels are dominant to biomass burning at the valley observatory and are slightly lower at the Huaytapallana observatory. These results demonstrate the need to promote mitigation actions to reduce emissions of BC and air pollution associated with forest fires and local anthropogenic activity.
Assuntos
Poluentes Atmosféricos , Poluição do Ar , Atmosfera , Monitoramento Ambiental , Fuligem , Peru , Poluentes Atmosféricos/análise , Fuligem/análise , Atmosfera/química , Poluição do Ar/estatística & dados numéricosRESUMO
Additive manufacturing is a technique that allows the construction of prototypes and has evolved a lot in the last 20 years, innovating industrial fabrication processes in several areas. In chemistry, additive manufacturing has been used in several functionalities, such as microfluidic analytical devices, energy storage devices, and electrochemical sensors. Theophylline and paracetamol are important pharmaceutical drugs where overdosing can cause adverse effects, such as tachycardia, seizures, and even renal failure. Therefore, this paper aims at the development of miniaturized electrochemical sensors using 3D printing and polylactic acid-based conductive carbon black commercial filament for theophylline and paracetamol detection. Electrochemical characterizations of the proposed sensor were performed to prove the functionality of the device. Morphological characterizations were carried out, in which chemical treatment could change the surface structure, causing the improvement of the analytical signal. Thus, the detection of theophylline at a linear range of 5.00-150 µmol L-1 with a limit of detection of 1.2 µmol L-1 was attained, and the detection of paracetamol at a linear range of 1.00-200 µmol L-1 with a limit of detection of 0.370 µmol L-1 was obtained, demonstrating the proposed sensor effectively detected pharmaceutical drugs.
Assuntos
Acetaminofen , Técnicas Eletroquímicas , Poliésteres , Fuligem , Teofilina , Acetaminofen/análise , Fuligem/química , Técnicas Eletroquímicas/métodos , Teofilina/análise , Poliésteres/química , Limite de Detecção , Impressão Tridimensional , MiniaturizaçãoRESUMO
Current methods for measuring black carbon aerosol (BC) by optical methods apportion BC to fossil fuel and wood combustion. However, these results are aggregated: local and non-local combustion sources are lumped together. The spatial apportioning of carbonaceous aerosol sources is challenging in remote or suburban areas because non-local sources may be significant. Air quality modeling would require highly accurate emission inventories and unbiased dispersion models to quantify such apportionment. We propose FUSTA (FUzzy SpatioTemporal Apportionment) methodology for analyzing aethalometer results for equivalent black carbon coming from fossil fuel (eBCff) and wood combustion (eBCwb). We applied this methodology to ambient measurements at three suburban sites around Santiago, Chile, in the winter season 2021. FUSTA results showed that local sources contributed â¼80% to eBCff and eBCwb in all sites. By using PM2.5 - eBCff and PM2.5 - eBCwb scatterplots for each fuzzy cluster (or source) found by FUSTA, the estimated lower edge lines showed distinctive slopes in each measurement site. These slopes were larger for non-local sources (aged aerosols) than for local ones (fresh emissions) and were used to apportion combustion PM2.5 in each site. In sites Colina, Melipilla and San Jose de Maipo, fossil fuel combustion contributions to PM2.5 were 26 % (15.9 µg m-3), 22 % (9.9 µg m-3), and 22 % (7.8 µg m-3), respectively. Wood burning contributions to PM2.5 were 22 % (13.4 µg m-3), 19 % (8.9 µg m-3) and 22% (7.3 µg m-3), respectively. This methodology generates a joint source apportionment of eBC and PM2.5, which is consistent with available chemical speciation data for PM2.5 in Santiago.
Assuntos
Poluentes Atmosféricos , Poluentes Atmosféricos/análise , Material Particulado/análise , Monitoramento Ambiental/métodos , Estações do Ano , Fuligem/análise , Combustíveis Fósseis/análise , Aerossóis/análise , Carbono/análiseRESUMO
Waste collection services are uncommon in rural areas of low-resource countries, causing waste accumulation and subsequent dumping and burning of garbage. Air pollution from household garbage burning, including plastics, has been observed in Jalapa, Guatemala in addition to household air pollution (HAP) from cooking. Adolescent girls often help with these cooking and household tasks, but little is known about their exposures. We characterized 24-h exposures to HAP and household garbage burning in adolescent girls by measuring fine particulate matter (PM2.5), black carbon (BC), urinary biomarkers of polycyclic aromatic hydrocarbons (PAHs), bisphenol A (BPA), and phthalates. We recruited 60 girls between 13 and 17 years of age who helped with cooking activities and lived with participants of the Household Air Pollution Intervention Network (HAPIN) trial. We recruited n = 30 girls each from the control (wood-burning stove) and intervention (liquefied petroleum gas stove) arms. We also measured real-time kitchen concentrations of BC in 20 homes (33%). PM2.5 and BC were measured in n = 21 control and n = 20 intervention participants. Median concentrations of personal PM2.5 and BC and kitchen BC were lower (p < 0.05) in the intervention arm by 87%, 80%, and 85%, respectively. PAH metabolite concentrations were lower (p < 0.001) for all nine metabolites in intervention (n = 26) compared to control participants (n = 29). Urinary BPA concentrations were 66% higher in participants who reported using cosmetics (p = 0.02), and phthalate concentrations were 63% higher in participants who had reported using hair products during the sample period (p = 0.05). Our results suggest that gas stoves can reduce HAP exposures among adolescents who are not primary cooks at home. Biomarkers of plastic exposure were not associated with intervention status, but some were elevated compared to age- and sex-matched participants of the National Health and Nutrition Examination Survey (NHANES).
Assuntos
Poluição do Ar em Ambientes Fechados , Poluição do Ar , Feminino , Humanos , Adolescente , Inquéritos Nutricionais , Poluição do Ar em Ambientes Fechados/análise , Guatemala , Poluição do Ar/análise , Material Particulado/análise , Fuligem , Culinária , Biomarcadores , População RuralRESUMO
This study presents the development of an electrochemical sensor, denoted as GCE/CB/SiAlSn, based on the modification of a glassy carbon electrode surface with the ternary oxide SiO2/Al2O3/SnO2 associated with carbon black, for direct determination of the neonicotinoid pesticide clothianidin in different matrices, such as environmental and food samples. Morphological characterization by the scanning electron microscopy technique, electroanalytical analyses using the cyclic voltammetry technique and differential pulse voltammetry are presented which demonstrated that the developed electrochemical platform presents high sensitivity in the electroanalytical clothianidin determination. The linear range studied was from 2.99 × 10-7 to 6.04 × 10-5 mol L-1, with an LOD of 2.47 nmol L-1. This high sensitivity was explained using the synergistic relationship between carbon black and ternary oxide that maximized the electroactive surface area of the GCE/CB/SiAlSn sensor. Interferent studies were performed that showed high selectivity of the sensor to the pesticide in the presence of Ca2+, K+, Na+, and Mg2+ and carbendazim, glyphosate, imidacloprid and thiamethoxam pesticides. The sensor was applied to real samples of tap water and apple juice obtaining recoveries from 91.0% to 103.0%.
Assuntos
Grafite , Óxidos , Óxidos/química , Grafite/química , Fuligem , Dióxido de Silício , NeonicotinoidesRESUMO
2,3-Dihydroxyphenol (DHP) is a phenolic compound that has been used as an additive in biodiesel to avoid the auto-oxidation of biofuels and also in the production of cosmetic products. However, this substance can be released into the environment during its manufacture, transport, disposal and industrial use and can be harmful to health due to its toxicity, and hence, monitoring its presence in different samples is very important. Therefore, this work describes an electroanalytical study of DHP using different carbon-based pastes prepared to evaluate which one would be more promising to be used as an electrochemical platform for DHP quantification. The materials studied (graphite, carbon black and carbon nanotubes) in this work were characterized by Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy and the Boehm method. Voltammetric studies showed that pure carbon black presented a higher current density for detecting DHP than the other materials tested (graphite, carbon black + graphite, carbon nanotubes, carbon nanotubes + graphite). In studying the medium's pH, the highest currents occurred in acid media and acetate buffer solutions. After optimizing the experimental parameters, it was possible to obtain a wide range of linear responses from 0.1 to 10 000 µmol L-1 for DHP and a good limit of detection (LOD) of 0.03 µmol L-1. The selectivity of the electrode was tested for different species that may be present in samples containing DHP. Finally, the electrode was applied to determine DHP in natural water and biodiesel samples, showing recovery values between 98 and 102%, indicating good accuracy.
Assuntos
Grafite , Nanotubos de Carbono , Biocombustíveis , Água , Nanotubos de Carbono/química , Grafite/química , FuligemRESUMO
Sulfanilamide (SFL) is used to prevent infections in honeybees. However, many regulatory agencies prohibit or establish maximum levels of SFL residues in honey samples. Hence, we developed a low-cost and portable electrochemical method for SFL detection using a disposable device produced through 3D printing technology. In the proposed approach, the working electrode was printed using a conductive filament based on carbon black and polylactic acid and it was associated with square wave voltammetry (SWV). Under optimized SWV parameters, linear concentration ranges (1-10 µmol L-1 and 12.5-35.0 µmol L-1), a detection limit of 0.26 µmol L-1 (0.05 mg L-1), and suitable RSD values (2.4% for inter-electrode; n = 3) were achieved. The developed method was selective in relation to other antibiotics applied in honey samples, requiring only dilution in the electrolyte. The recovery values (85-120%) obtained by SWV were statistically similar (95% confidence level) to those obtained by HPLC, attesting to the accuracy of the analysis and the absence of matrix interference.
Assuntos
Mel , Fuligem , Animais , Fuligem/química , Sulfanilamida , Eletroquímica , Eletrodos , Técnicas Eletroquímicas , Carbono/químicaRESUMO
The processing of coal tar pitch (CTP) to produce clean fuel gas and carbon black (CB) is studied in a plasma reactor equipped with a direct-current plasma torch. The composition of the gas produced and energy costs were estimated theoretically for the CTP pyrolysis and gasification processes by two oxidants, namely oxygen and water vapor. We have found that the main gaseous compounds obtained in the pyrolysis and gasification processes are hydrogen (H2), carbon monoxide (CO), and very often carbon dioxide (CO2). For the pyrolysis case, the mean value of the synthesis gas concentration reaches a major value of 98 vol.% (H2 - 81 vol.%, CO - 17. vol.%). However, only 23% of the initial CTP is transformed into gas phase at 1100â K and its content increases up to 37.4% at a temperature of 3000â K. For oxygen gasification, the syngas quantity is little less compared to the pyrolysis case and attains 96.6 vol.% (H2 - 26.5 vol.%, CO - 70.1 vol.%) for T > 1100â K. An intermediate syngas content for the water steam gasification is 97.8 vol.% (with H2 - 55.8 vol.% and CO - 42.0 vol.%). The CB produced was composed of well-defined spherical particles of 30-nm size. Furthermore, it is composed of carbon (98.2%), and followed by oxygen (1.8%) with a surface area of 97 m2 g-1. The thermal plasma system shows high efficiency in conversion of CTP into high-value-added products.
Assuntos
Alcatrão , Gases em Plasma , Fuligem , Gases , Vapor , Hidrogênio , Oxigênio , BiomassaRESUMO
BACKGROUND: The SARS-CoV-2 pandemic has temporarily decreased black carbon emissions worldwide. The use of multi-wavelength aethalometers provides a quantitative apportionment of black carbon (BC) from fossil fuels (BCff) and wood-burning sources (BCwb). However, this apportionment is aggregated: local and non-local BC sources are lumped together in the aethalometer results. METHODS: We propose a spatiotemporal analysis of BC results along with meteorological data, using a fuzzy clustering approach, to resolve local and non-local BC contributions. We apply this methodology to BC measurements taken at an urban site in Santiago, Chile, from March through December 2020, including lockdown periods of different intensities. RESULTS: BCff accounts for 85% of total BC; there was up to an 80% reduction in total BC during the most restrictive lockdowns (April-June); the reduction was 40-50% in periods with less restrictive lockdowns. The new methodology can apportion BCff and BCwb into local and non-local contributions; local traffic (wood burning) sources account for 66% (86%) of BCff (BCwb). CONCLUSIONS: The intensive lockdowns brought down ambient BC across the city. The proposed fuzzy clustering methodology can resolve local and non-local contributions to BC in urban zones.